Open AccessThe rheology property of organogels based on 3D helical nanofilament bnetworks self-assembled by bent-core liquid crystals
Author(s) -
Xing-Zheng Wang,
Chenjing Yang,
LiHeng Cai,
Chen Dong
Publication year - 2020
Publication title -
wuli xuebao
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.199
H-Index - 47
ISSN - 1000-3290
DOI - 10.7498/aps.69.20200332
Subject(s) - materials science , rheology , viscoelasticity , hexadecane , bent molecular geometry , soft matter , liquid crystal , core (optical fiber) , chemical physics , modulus , molecule , phase (matter) , dynamic mechanical analysis , chemical engineering , composite material , polymer , organic chemistry , chemistry , colloid , optoelectronics , engineering
In the B4 phase of bent-core liquid crystals, smectic layers of tilted achiral bent-core molecules are chiral and polar, which, driven by intra-layer structural mismatch, eventually twist into helical nanofilaments. We design a NOBOW/hexadecane organogel system, which is different from traditional organogel system, and the studied organogels show reversible gel-liquid transitions under temperature cycles. At high temperature, the NOBOW molecules dissolve in hexadecane and the storage modulus and viscous modulus show typical liquid characteristics. At low temperature, the mobility of NOBOW molecules decreases and the storage modulus of the organogels increases as the temperature decreases. We conduct a rheology experiment to systematically investigate the viscoelasticity of the organogel to understand the property of the organogel and develop the application in soft matter. The viscoelastic studies of the organogels reveal that the helical nanofilaments are internally strained and their 3D networks are relatively stiff, which provides an in-depth insight into the properties of the organogels and paves the way for their applications in soft matter.