Open AccessTheoretical study of photovoltaic performance for inverted halide perovskite solar cells
Author(s) -
Ao Zhang,
Chunxiu Zhang,
Yunlin Chen,
Chunmei Zhang,
Meng Tao
Publication year - 2020
Publication title -
wuli xuebao
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.199
H-Index - 47
ISSN - 1000-3290
DOI - 10.7498/aps.69.20200089
Subject(s) - non blocking i/o , materials science , photovoltaic system , perovskite (structure) , energy conversion efficiency , heterojunction , work function , optoelectronics , nanotechnology , crystallography , chemistry , electrical engineering , catalysis , layer (electronics) , biochemistry , engineering
The existence of serious hysteresis effect for regular perovskite solar cells (PSCs) will affect their performances, however, the inverted PSCs can significantly suppress the hysteresis effect. To data, it has been very rarely reported to simulate the inverted planar heterojunction PSCs. In this paper, the effects of hole transport material (HTM), electron transport material (ETM), and ITO work function on performance of inverted MAPbI 3 solar cells are carefully investigated in order to design the high-performance inverted PSCs. The inverted MAPbI 3 solar cells using Cu 2 O, CuSCN, or NiO x as HTM, and PC 61 BM, TiO 2 , or ZnO as ETM are simulated with the program AMPS-1D. Simulation results reveal that i) the inverted MAPbI 3 solar cells choosing NiO x as HTM can effectively improve the photovoltaic performance, and the excellent photovoltaic performance obtained by using TiO 2 as ETM is almost the same as by using ZnO as ETM; ii) the ITO work function increasing from 4.6 eV to 5.0 eV can significantly enhance the photovoltaic performances of Cu 2 O— based and CuSCN— based inverted MAPbI 3 solar cells, and the NiO x — based inverted MAPbI 3 solar cells have only a minor photovoltaic performance enhancement; iii) based on the reported ITO work function between 4.6 eV and 4.8 eV, the maximum power conversion efficiency (PCE) of 27.075% and 29.588% for CuSCN— based and NiO x — based inverted MA PbI 3 solar cells are achieved when the ITO work function reaches 4.8 eV. The numerical simulation gives that the increase of hole mobility in CuSCN and NiO x for ITO/CuSCN/MAPbI 3 /TiO 2 /Al and ITO/NiO x /MAPbI 3 /TiO 2 /Al can greatly improve the device performance. Experimentally, the maximum hole mobility 0.1 cm 2 ·V –1 ·s –1 in CuSCN restricts the photovoltaic performance improvement of CuSCN— based inverted MAPbI 3 solar cells, which means that there is still room for the improvement of cell performance through increasing the hole mobility in CuSCN. It is found that NiO x with a reasonable energy-band structure and high hole mobility 120 cm 2 ·V –1 ·s –1 is an ideal HTM in inverted MAPbI 3 solar cells. However, the increasing of electron mobility in TiO 2 cannot improve the device photovoltaic performance of inverted MAPbI 3 solar cells. These simulation results reveal the effects of ETM, HTM, and ITO work function on the photovoltaic performance of inverted MAPbI 3 solar cells. Our researches may help to design the high-performance inverted PSCs.