Open AccessQuantum coherence measurement with femtosecond time-resolve two-dimensional electronic spectroscopy: principles, applications and outlook
Author(s) -
Yuxiang Weng,
Zhuan Wang,
Hailong Chen,
Xuan Leng,
Ruidan Zhu
Publication year - 2018
Publication title -
wuli xuebao
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.199
H-Index - 47
ISSN - 1000-3290
DOI - 10.7498/aps.67.20180783
Subject(s) - coherence (philosophical gambling strategy) , spectroscopy , femtosecond , femtochemistry , electron spectroscopy , quantum , physics , electronic structure , coherent spectroscopy , computer science , optics , quantum mechanics , laser , coherent anti stokes raman spectroscopy , raman scattering , raman spectroscopy
Two-dimensional electronic spectroscopy is a kind of nonlinear optical spectroscopy with both high time resolution and high frequency resolution. It can be used to observe the complex dynamics of a condensed molecular system. Meanwhile it is a very powerful tool to study the coherence between the electronic states or electronic and vibration states. In 2007, Flemming's group reported the long-lived quantum coherence observed in the energy transfer process in the light-harvesting antenna protein complex Fenna-Matthews-Olson at 77 K by means of two-dimensional electronic spectroscopy. Though it has been proved not to arise from the pure electronic coherence later, this discovery has greatly stimulated the exploration of the coherent energy transfer pathways possibly existing in the natural and artificial photosynthetic systems, and this is still a very active area nowadays. Here in this paper we briefly review the principle and set-up of the two-dimensional electronic spectroscopy, and also some of its applications in investigating coherent energy transfer in the photosynthetic and artificial systems, aiming to bring this novel spectroscopic tool into a wider application.