Open AccessInvestigation of ultrafast relaxation dynamic process of water-soluble TGA-CdTe quantum dots
Author(s) -
Han Yuan-chun,
Tmurbagan Bao
Publication year - 2015
Publication title -
wuli xuebao
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.199
H-Index - 47
ISSN - 1000-3290
DOI - 10.7498/aps.64.113201
Subject(s) - excited state , materials science , cadmium telluride photovoltaics , fluorescence , exciton , relaxation (psychology) , quantum dot , femtosecond , ultrafast laser spectroscopy , time resolved spectroscopy , absorption (acoustics) , molecular physics , optoelectronics , atomic physics , optics , laser , condensed matter physics , chemistry , physics , psychology , social psychology , composite material
In the present paper, we study the average fluorescence lifetimes, detected by using the time-correlated single-photon-counting (TCSPC) technique, of three thioglycolic acid-capped CdTe quantum dots (TGA-CdTe QDs), which are 6 ns, 9 ns and 11 ns; and the fluorescence kinetic process includes two parts:the slow process and the fast process. With the increase of the particle size, the slow process becomes longer, but the fast process becomes shorter. Afterwards, by using both femtosecond transient absorption and fluorescence up-conversion time-resolved spectrum techniques, we have investigated the interband relaxation process of three TGA-CdTe QD samples, with the nanoparticle diameters of 2.3, 2.8 and 3.5 nm. Investigation indicates that for the three QD samples, exciton filling rate becomes slower in the highest excited state and the lowest excited state, among them, the time of exciton filling increases from 0.33 to 0.79 ps for the highest excited state, while the time of exciton filling increases from 0.53 ps to 1 ps for the lowest excited state. Moreover, the two kinds of experiment provide complementary information and obtain the full image of interband relaxation process. Result shows that the bleach recovery of the 1 S transition shows an initial rise, but the fluorescence up-conversion signal for the 1 S transition is slower in rise time, which can provide help in the application of optoelectronic devices.