Open AccessPhase transition, electronic and optical properties of Si3N4 new phases at high pressure with density functional theory
Author(s) -
Bo Yu,
Chen Dong
Publication year - 2014
Publication title -
wuli xuebao
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.199
H-Index - 47
ISSN - 1000-3290
DOI - 10.7498/aps.63.047101
Subject(s) - materials science , band gap , semiconductor , phase transition , dielectric , density functional theory , condensed matter physics , dielectric function , phase (matter) , direct and indirect band gaps , electronic structure , electronic band structure , reflectivity , hexagonal crystal system , optoelectronics , optics , physics , computational chemistry , chemistry , crystallography , quantum mechanics
Characteristics of the hexagonal polymorph Si3N4 i.e., phase transition, electronic and optical properties (band structure, dielectric function, reflectivity and energy loss function) are investigated by the first-principles pseudo-potential method. The results suggest that it is feasible that the P6 transition takes place at room temperature. The critical pressures of the P6 and P6 transformations are 42.9 and 47.7~GPa, respectively. The phase transition from P6 is accompanied by the volume shrinkage. The calculated results also show that the P6 and P6' phases belong to direct bandgap and indirect bandgap semiconductors, respectively. The calculated band gaps are 4.98 and 4.01 eV for the P6 and P6' phases, respectively. Besides, the static dielectric constants are also obtained. The reflectivity shows that the two phases can serve as the shielding and detecting devices for ultraviolet radiation and they have optical transparent behaviors in the visible light region.