Open AccessTheoretical study of electronic structure and optical properties of OsnN0,(n=1 6) clusters
Author(s) -
张秀荣,
吴礼清,
饶倩
Publication year - 2011
Publication title -
wuli xuebao
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.199
H-Index - 47
ISSN - 1000-3290
DOI - 10.7498/aps.60.083601
Subject(s) - natural bond orbital , atom (system on chip) , density functional theory , cluster (spacecraft) , atomic physics , magnetic moment , materials science , ab initio , raman spectroscopy , electronic structure , ferromagnetism , aromaticity , molecular physics , physics , condensed matter physics , molecule , optics , quantum mechanics , computer science , programming language , embedded system
The possible geometrical and electronic structures of (OsnN)0,(n=16) clusters are optimized by using the density functional theory (B3LYP) at the LANL2DZ level. For the ground state structures of (OsnN)0,(n=16) clusters, The magnetic properties, the natural bond orbit (NBO), the spectrum and the aromatic characteristics are analyzed. The calculated results show that the magnetic moment of OsnN- cluster is quenched at n=1 and 5. Reversed ferromagnetic coupling between Os atom and N atom takes place in Os2N and Os4N0, clusters. The NBO charge distribution of clusters depends on the relative position of the atom, for example, the charge transfer happening to N atoms in the endpoint is more obvious than that happening to the N atoms in the middle. There are obvious vibration peaks in IR and Raman spectra of (OsnN)0,(n=16) clusters. The aromaticity of Os5N- cluster is the strongest.