Open AccessExperiment study of orientation and reorientation quantum dynamics of single dye molecules at room temperature
Author(s) -
Guofeng Zhang,
Cheng Feng-Yu,
Suotang Jia,
Jian Sun,
Xiao Liu,
Fang Zhang
Publication year - 2009
Publication title -
wuli xuebao
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.199
H-Index - 47
ISSN - 1000-3290
DOI - 10.7498/aps.58.2364
Subject(s) - molecule , dipole , materials science , polarization (electrochemistry) , fluorescence , molecular physics , polymer , confocal , photon , optics , chemical physics , physics , chemistry , quantum mechanics , composite material
We have studied experimentally the dipole orientation and reorientation dynamics of single dye molecules at room temperature. The dipole rotation of individual dye molecules which are physisorbed to glass and embedded in spin-cast polymer films is measured with the confocal scanning optical microscopy and the method of fluorescence polarization analysis, the probability of reorientation of single molecules found to be about 5%—9% when embedded in polymer, and about 26% when absorbed to glass by using the statistic analysis. It is found the quantum jumps for molecule dipole reorientation are distributed in several different polarization states by measuring the polarization degree of fluorescent photons.