Rovibronic spectrum of N2O+ ion at the A2Σ+ state | Zendy

Hua Wang | Zendy; Shilin Liu | Zendy; Jie Liu | Zendy; Wang Feng-Yan | Zendy; Jiang Bo | Zendy; Yang Xue-Ming | Zendy

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Rovibronic spectrum of N2O+ ion at the A2Σ+ state

Author(s) -

Hua Wang,

Shilin Liu,

Jie Liu,

Wang Feng-Yan,

Jiang Bo,

Yang Xue-Ming

Publication year - 2008

Publication title -

acta physica sinica

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.199

H-Index - 47

ISSN - 1000-3290

DOI - 10.7498/aps.57.796

Subject(s) - atomic physics , excited state , ion , ionization , excitation , materials science , laser , resonance enhanced multiphoton ionization , range (aeronautics) , photoionization , physics , optics , quantum mechanics , composite material

The rotational structures of the photofragment excitation spectrum of N2O+(A2Σ+) at high vibrational levels have been studied experimentally. The parent N2O+(X2Π) ions were prepared by (3+1) resonance-enhanced multiphoton ionization of jet-cooled N2O molecules by 36055nm laser beamand were excited by another laser to the predissociative A2Σ+ state in the range of 280—320nm. Two types of rotational transitioni.e.2Σ+←2Π and 2Π←2Πhave been clearly observed for a series of vibronic transitions. The rotational constants and spin splitting constants have been obtained from the spectral analysis.

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