Open AccessFirst principles study of potential energy curves of NiTi alloy
Author(s) -
Jiang Zhen-Yi,
Shengtao Li
Publication year - 2006
Publication title -
wuli xuebao
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.199
H-Index - 47
ISSN - 1000-3290
DOI - 10.7498/aps.55.6032
Subject(s) - pseudopotential , materials science , nickel titanium , phase (matter) , alloy , condensed matter physics , diffusionless transformation , martensite , potential energy , shape memory alloy , atomic physics , thermodynamics , metallurgy , physics , microstructure , quantum mechanics
The potential energy curves of B2 and B19′ phase for NiTi alloys were investigated with the norm-conserving and plane-wave ultrasoft pseudopotential in the local density approximation. Our results reveals that the B19′ phase is more stable than the B2 phase at absolute zero temperature due to lower potential energy of the former. In the B2 phase, the alloying atoms Au and Fe (at Ni site) occupy the equilibrium positions, whereas Ti, Zr and Al (at Ti site) and Ni atoms are displaced from their equilibrium positions. In the B19′ phase, all the above atoms are exactly located at the equilibrium positions. The martensitic transformation may mostly be ascribed to the non-global minimum positions that the Ni and Ti atoms occupy.