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Vacuum ultraviolet spectroscopic properties and 4f5d state of Pr3+doped YAG
Author(s) -
Chao Meng,
Shihua Huang,
Fangtian You,
Chang JianJun,
Hongshang Peng,
Tao Ye,
Guobin Zhang
Publication year - 2005
Publication title -
wuli xuebao
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.199
H-Index - 47
ISSN - 1000-3290
DOI - 10.7498/aps.54.5468
Subject(s) - excited state , materials science , excitation , synchrotron radiation , yttrium , atomic physics , phonon , exciton , vacuum ultraviolet , doping , emission spectrum , analytical chemistry (journal) , spectral line , chemistry , condensed matter physics , optics , physics , optoelectronics , quantum mechanics , astronomy , chromatography , metallurgy , oxide
Yttrium aluminum garnet (YAG): Pr3+ is synthesized by codeposition me thod. Vacuum ultraviolet (VUV) excitation and emission spectra of YAG: Pr3+ at different temperatures are measured using synchrotron radiation as an excitation source. We analyze the transition process after excitation to 4f5d en ergy band and estimate the Huang-Rhys factor S and phonon energy ηω of YAG: Pr 3+ by multi-phonon relaxation. Emission of self-trapped exciton (STE) and 3P0→3H4,5,6 emission transferr ed from the STE energy appear when YAG: Pr3+is excited by 170nm, whic h is a different transition process from those excited by 240nm and 289nm.

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