Open AccessThe microstructure and properties of tetrahedral amorphous carbon films deposited by filtered arc with accelerating at different energetic grades
Author(s) -
Jiaqi Zhu,
Jinghe Wang,
Sheng Meng,
Jiecai Han,
Liansheng Zhang
Publication year - 2004
Publication title -
wuli xuebao
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.199
H-Index - 47
ISSN - 1000-3290
DOI - 10.7498/aps.53.1150
Subject(s) - microstructure , materials science , tetrahedron , amorphous solid , amorphous carbon , carbon fibers , arc (geometry) , engineering physics , chemical engineering , chemical physics , composite material , crystallography , physics , geometry , chemistry , composite number , mathematics , engineering
Tetrahedral amorphous carbon (ta-C) films were deposited on single crystalline silicon by accelerating the species with different impinging energetic grades produced by static-electricity pulse substrate bias from 0 to -2000 V. The microstructure of the ta-C films consist of amorphous sp3 hybridization skeleton enchased with sp2 clusters with sizes less than 1 nm by visible Raman measurement. At low energetic grade, sp3-rich energetic window, and sub-high energetic grade, the more the content of sp3 in the film, the smoother the surface of the film. The relationship between the impinging energy of the species and the surface morphology can be illustrated perfectly in the light of subimplantation growth mechanism. Nevertheless, at high energetic grade, the impinging ions with appropriate energy and angle can sputter and smoothen the surface, even the roughness is lower than the surface of the films with the most sp3. The hardness and Young's modulus of the films deposited at high energetic grade (-2000 V) are higher than those of the films prepared on the floating conditions. At the same time, the critical scratching load of the films deposited with the substrate bias of -2000 V is even larger than the one of the sp3-rich films.