
THE DESORPTION AND DISSOCIATION OF ETHYLENE (C2H4) ON Ru(1 010) SURFACE
Author(s) -
Zhuang You-Yi,
Wu Yue,
Jianhua Zhang,
Hanjie Zhang,
Jian Wang,
Haiyang Li,
He Pi-Mo,
Bao Shi-Ning
Publication year - 2000
Publication title -
wuli xuebao
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.199
H-Index - 47
ISSN - 1000-3290
DOI - 10.7498/aps.49.2101
Subject(s) - ethylene , x ray photoelectron spectroscopy , dehydrogenation , desorption , acetylene , ultraviolet photoelectron spectroscopy , binding energy , dissociation (chemistry) , photochemistry , adsorption , thermal desorption spectroscopy , materials science , thermal desorption , chemistry , catalysis , organic chemistry , atomic physics , nuclear magnetic resonance , physics
The ethylene (C2H4) adsorbed on Ru(1010) surface has been studied by X-ray photoelectron spectroscopy (XPS),thermal desorption spectroscop y (TDS) and ultraviolet photoelectron spectroscopy (UPS).The results show that e thylene absorbs in molecular state on Ru(1010) surface stably below 200K.The deh ydrogenation of ethylene occurs at 200K.The main product of the dehydrogenation of the absorbed ethylene is the acetylene (C2H2). After th e dehydrogenation of the absorbed ethylene,the C1s shifts 0.3eV to low binding e nergy level,and the binding energies of σCC and σCH bond have an increase of 0.5eV and 1.1eV respectively.