DETERMINATION OF 3d AND 5s RYDBERG STATES OF SF2 RADICAL | Zendy

ZHANG QUN | Zendy; SHU JI-NAN | Zendy; Ning Li | Zendy; Jinghua Dai | Zendy; Limin Zhang | Zendy; LI QUAN-XIN | Zendy

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DETERMINATION OF 3d AND 5s RYDBERG STATES OF SF2 RADICAL

Author(s) -

ZHANG QUN,

SHU JI-NAN,

Ning Li,

Jinghua Dai,

Limin Zhang,

LI QUAN-XIN

Publication year - 1998

Publication title -

acta physica sinica

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.199

H-Index - 47

ISSN - 1000-3290

DOI - 10.7498/aps.47.1776

Subject(s) - rydberg formula , atomic physics , spectroscopy , materials science , radical , quantum defect , spectral line , supersonic speed , rydberg state , molecular physics , physics , ionization , chemistry , ion , quantum mechanics , organic chemistry , thermodynamics

A pulsed dc discharge in a pulsed supersonic beam has been developed as an efficient source of producing free radicals. Spectra of the SF2 radical were observed between 272 and 294 nm by (2+1) resonance-enhanced multiphoton ionizition (REMPI) spectroscopy. Vibrational progressions associat-ed with 3d and 5s Rydberg states were assigned. The spectroscopic values ω1 (a1, symmetric stretch-ing), band origin T0 and quantum defect δ of these Rydberg states were reported.

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