Open AccessFERMI RESONANCES AND VIBRATIONAL SPECTRUM FOR METHANE
Author(s) -
Xi-Wen Hou,
Mi Xie,
ZhongQi Ma
Publication year - 1997
Publication title -
wuli xuebao
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.199
H-Index - 47
ISSN - 1000-3290
DOI - 10.7498/aps.46.1073
Subject(s) - fermi resonance , fermi gamma ray space telescope , physics , annihilation , realization (probability) , bending , atomic physics , spectrum (functional analysis) , molecular vibration , methane , condensed matter physics , spectral line , raman spectroscopy , quantum mechanics , chemistry , statistics , mathematics , organic chemistry , thermodynamics
The boson realization model with Fermi resonances is used for explaining both stretching and bending vibrational spectra in methane. The interactions between stretching and bending vibrations are described by Td symmetric Fermi resonance terms that couple one creation (or annihilation) operator of stretching vibrations with two annihilation (or creation) operators of bending ones. This model provides a ten-parameter fit to the published experimental vibrational- eigenvalues of methane with the root-mean-square energy deviation 12.38cm.