Open AccessCO AND O CHEMISORPTION ON DISORDERED BINARY ALLOY NiCu
Author(s) -
YANG Zong-Xian,
Tao Zhang
Publication year - 1991
Publication title -
wuli xuebao
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.199
H-Index - 47
ISSN - 1000-3290
DOI - 10.7498/aps.40.269
Subject(s) - chemisorption , alloy , materials science , matrix (chemical analysis) , binary number , binary alloy , condensed matter physics , thermodynamics , chemistry , adsorption , physics , metallurgy , composite material , mathematics , arithmetic
One-dimensional tight-binding model and the one-electron chemisorption theory are used to calculate the chemisorption energy of CO or O on NixCu1-x surface under the average T-matrix approximation. It is found that the chemisorption of CO and O on NixCu1-x are strengthened with the increase of bulk Ni concentration. The Cu segragation to the NiCu alloy surface may weaken the chemisorption.