Open AccessINFLUENCE OF CHLORIDE IONS ON SERS IN Ag SOL
Author(s) -
Fu Shi-You,
Pengxiang Zhang,
Xiuying Li
Publication year - 1991
Publication title -
wuli xuebao
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.199
H-Index - 47
ISSN - 1000-3290
DOI - 10.7498/aps.40.1915
Subject(s) - chloride , pyridine , ion , adsorption , absorption (acoustics) , materials science , inorganic chemistry , chemistry , organic chemistry , composite material , metallurgy
The influence of chloride ions on SERS of PABA (p-aminobenzioc acid) and pyridine in Ag sol were discussed. SERS of PABA in Ag sol, the influence of chloride ions on and the time dependence of SERS intensities were obser ved. It was found that the decrease of SERS intensity was caused by that the solid like phase adsorption of PABA was destroyed and the molecular adsorption state was changed dut to the competitive adsorption of chloride ions. Besides, the influence of chloride ions on the time dependence of SERS intensities of a mixture of PABA/Ag sol and pyridine/Ag sol and on the light absorption of PABA and pyridine in Ag sol were studied. These experimtnts show that the influence of chloride ions on SERS in our system are mainly chemical.