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PHYSICAL INVESTIGATION ON TUNGSTEN BRONZE CRYSTALS
Author(s) -
Li-Man Li,
Gang Wang
Publication year - 1989
Publication title -
wuli xuebao
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.199
H-Index - 47
ISSN - 1000-3290
DOI - 10.7498/aps.38.849
Subject(s) - bronze , tetragonal crystal system , materials science , tungsten , raman spectroscopy , ionic bonding , ion , diffraction , electrolysis , crystal structure , intercalation (chemistry) , ionic conductivity , crystallography , inorganic chemistry , optics , chemistry , electrode , metallurgy , physics , organic chemistry , electrolyte
KxWO3,NayWO3 and KxNayWO3 crystals were prepared by fused salt electrolysis. The X-ray diffraction, Raman, Infra-red we may conclude and condutivity me. asurements were made. From our results that KxNayWO3 is formed by intercalating Na+ ions into the tetragonal KxWO3 crystal lattice. A mechanism of ionic conduction is suggested.