ON THE INTERACTION OF H2 (X1∑g+)—H2(E1∑g+) SYSTEM | Zendy

Lü YAN-NAN | Zendy; HUANG ZU-QIA | Zendy

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ON THE INTERACTION OF H2 (X1∑g+)—H2(E1∑g+) SYSTEM

Author(s) -

Lü YAN-NAN,

HUANG ZU-QIA

Publication year - 1989

Publication title -

acta physica sinica

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.199

H-Index - 47

ISSN - 1000-3290

DOI - 10.7498/aps.38.1510

Subject(s) - wave function , excited state , atomic physics , ground state , range (aeronautics) , physics , potential energy , energy (signal processing) , state (computer science) , materials science , quantum mechanics , composite material , algorithm , computer science

A perturbative calculation for the long-range and intermediate interactions between excited state H2(E1∑g+) and ground state H2(X1∑g+) in the crossed geometry is performed by using a trial wavefunction depending on the interelectronic distance explicitly. According to the results, there is a potential energy barrier around the inter-molecular separation D = 6.5α0. Inside the barrier, there shows a strong chemical bond behavior.

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