DIELECTRIC PROPERTIES OF BIS-(p-TOLUENE SULPHONATE) OF 2,4-HEXADIYNE-l,6-DIAL (TS) AND EFFECT OF THE SOLID STATE POLYMERIZATION | Zendy

Yaozhong Ruan | Zendy; Liping Li | Zendy; Pingsheng He | Zendy; Gang Yao | Zendy

Open Access

DIELECTRIC PROPERTIES OF BIS-(p-TOLUENE SULPHONATE) OF 2,4-HEXADIYNE-l,6-DIAL (TS) AND EFFECT OF THE SOLID STATE POLYMERIZATION

Author(s) -

Yaozhong Ruan,

Liping Li,

Pingsheng He,

Gang Yao

Publication year - 1989

Publication title -

acta physica sinica

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.199

H-Index - 47

ISSN - 1000-3290

DOI - 10.7498/aps.38.149

Subject(s) - dielectric , polymerization , materials science , polymer , toluene , crystal (programming language) , solid state , polymer chemistry , chemistry , organic chemistry , composite material , optoelectronics , computer science , programming language

The temperature dependence of the dielectric constant of monomer single crystal TS has been determined for the range 77-300 K, two anomalies have been observed near 160 K and 203 K. The variation of the dielectric constant of TS during thermal solid state polymerization is obtained. It the initial stage of polymerization, the dielectric constant decreases slowly; when sample conversion to polymer exceeds 30%, the dielectric constant increases rapidly. We suggest that this behavior may be related to side-group and π-electron and hend explain the results qualitativly.

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