Open AccessTHE STATISTICAL THEORY OF CHEMICAL REACTIONS
Author(s) -
Huo Yu-Ping,
Hu Xi-Wei
Publication year - 1983
Publication title -
wuli xuebao
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.199
H-Index - 47
ISSN - 1000-3290
DOI - 10.7498/aps.32.599
Subject(s) - statistical theory , statistical physics , operator (biology) , probability density function , function (biology) , distribution function , projection (relational algebra) , spectrum (functional analysis) , physics , quantum mechanics , computer science , mathematics , statistics , algorithm , biochemistry , chemistry , repressor , evolutionary biology , biology , transcription factor , gene
In this article, a quantum statistical theory of fluctuation in chemical reaction systems has been developed. Starting from the Liouville equation, the equation for characteristic function and distribution function of density fluctuation has been obtained by projection operator method. The results confirm our previous phenomeno-logical theory. Finally, the correction terms of statistical theory and its influences on spectrum of fluctuation waves has been discussed.