Open AccessTHE CRYSTAL STRUCTURE OF DIMETHYL SULPHOXIDE COMPLEX OF YTTRIUM
Author(s) -
Yuan Lin,
Ninghai Hu,
Zhou Qinglian,
Shuzhen Liu,
Shi En-Dong,
Mingyi Wang
Publication year - 1983
Publication title -
wuli xuebao
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.199
H-Index - 47
ISSN - 1000-3290
DOI - 10.7498/aps.32.400
Subject(s) - yttrium , monoclinic crystal system , diffractometer , crystal structure , crystallography , diffraction , materials science , atom (system on chip) , x ray crystallography , physics , chemistry , optics , computer science , metallurgy , embedded system , oxide
The crystal of dimethyl sulphoxide complex of yttrium [Y(NO33·3DMSO] belongs to the monoclinic system, α= 13.604(4)?, b= 12.669(4)?, c= 11.554(2)?, β= 100.14(4)° and Z=4. The space group is P21/n. The diffraction data were collected using PW-1100 four-circle diffractometer. The number of independent diffraction data amounts to 3615. The structure was solved by heavy-atom method. Structure parameters were refined by full matrix and block diagonal least square method to a final R = 0.080. The result of structure analysis establishes that the polyhedral coordination of " three-headger triprism" is formed by nine oxygen atoms surrounding the Y cation. The distances between the yttrium and the coordinating oxygens are Y-ODMSO = 2.285?, Y-ONO3-= 2.460?.