PARAMAGNETIC RESONANCE STUDY ON TRANSITION METAL IONS IN PHOSPHATE, FLUOROPHOSPHATE AND FLUORIDE GLASSES(I)——Cr3+,Mo3+ | Zendy

Gan Fuxi | Zendy; He Deng | Zendy; LIU HUI-MING | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Open Access

PARAMAGNETIC RESONANCE STUDY ON TRANSITION METAL IONS IN PHOSPHATE, FLUOROPHOSPHATE AND FLUORIDE GLASSES(I)——Cr3+,Mo3+

Author(s) -

Gan Fuxi,

He Deng,

LIU HUI-MING

Publication year - 1982

Publication title -

acta physica sinica

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.199

H-Index - 47

ISSN - 1000-3290

DOI - 10.7498/aps.31.404

Subject(s) - fluoride , ion , phosphate , paramagnetism , electron paramagnetic resonance , materials science , transition metal , phosphate glass , hamiltonian (control theory) , inorganic chemistry , nuclear magnetic resonance , chemistry , condensed matter physics , physics , mathematical optimization , biochemistry , mathematics , organic chemistry , catalysis

The ESR of Cr3+ in phosphate, fluorophosphate and fluoride glasses has been studied. The effective g factors of Cr3+ have been calculated with the Spin-Hamil-tonian. It is pointed out that the low-field spectra resulted mainly from transition between two Kramers doublets. Hamiltonian parameters have been determined: D=0.15-0.4 cm-1, E/D=0.15-0.3; zero-field splitting: 0.3-0.8 cm-1. In this paper, the ESR of Mo3+ ion in phosphate glass is also reported.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research