DETERMINATION OF CRYSTAL STRUCTURE OF BENZOYL PERFLUORO-PROPENYL METHYLENE TRIPHENY-LARSORANCE (YLID-VI) | Zendy

ZHENG QI-TAI | Zendy; ZHENG CHAO-DE | Zendy; SHEN FU-LING | Zendy; BAI XION-LING | Zendy; ZHONG FU-MING | Zendy

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DETERMINATION OF CRYSTAL STRUCTURE OF BENZOYL PERFLUORO-PROPENYL METHYLENE TRIPHENY-LARSORANCE (YLID-VI)

Author(s) -

ZHENG QI-TAI,

ZHENG CHAO-DE,

SHEN FU-LING,

BAI XION-LING,

ZHONG FU-MING

Publication year - 1981

Publication title -

acta physica sinica

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.199

H-Index - 47

ISSN - 1000-3290

DOI - 10.7498/aps.30.1681

Subject(s) - monoclinic crystal system , propenyl , methylene , crystal structure , molecule , crystallography , chemistry , crystal (programming language) , atom (system on chip) , carbon atom , stereochemistry , medicinal chemistry , organic chemistry , ring (chemistry) , computer science , programming language , embedded system

Benzoyl Perfluoro-propenyl Methylene Triphenglarsorance (Ylid-VI) crystal is colourless and transparent. The space group is C2H5-P21/a. The crystal belongs to monoclinic system. The parameters of unit cell are a = 10.365 (8)?, b = 29.106 (4)?, c = 8.630 (8)?, β = 107.20 (28)°. There are four molecules in an unit cell (z = 4). The intensity data were collected on PW-1100 four circle diffraetometer, the total number diffraction amounts to 4966. The Ylid-VI crystal structure has been refined by means of block matrix least square method, R = 0.067.The molecular structure of Ylid-VI indicats that there occurs a eletronic transition between the arsenic atom and the carbon atom in the methene.

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