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Validity of Dynamic Light Scattering Method to Analyze a Range of Gold and Copper Nanoparticle Sizes Attained by Solids Laser Ablation in Liquid
Author(s) -
Yuri Golubenko,
Alexander Savkin,
Tatiana Sidorovnina,
В. С. Тимошенко
Publication year - 2014
Publication title -
nauka i obrazovanie
Language(s) - English
Resource type - Journals
ISSN - 1994-0408
DOI - 10.7463/1014.0730527
Subject(s) - laser ablation , copper , materials science , nanoparticle , ablation , colloidal gold , dynamic light scattering , range (aeronautics) , laser , laser ablation synthesis in solution , light scattering , scattering , optics , analytical chemistry (journal) , nanotechnology , chromatography , chemistry , metallurgy , physics , composite material , laser power scaling , x ray laser , engineering , aerospace engineering

Nanoparticles of metals possess a whole series of features, concerned with it’s sizes, this leads to appearing or unusual electromagnetic and optical properties, which are untypical for particulates.

An extended method of receiving nanoparticles by means of laser radiation is pulse laser ablation of hard targets in liquid medium.

Varying the parameters of laser radiation, such as wavelength of laser radiation, energy density, etc., we can operate the size and shape of the resultant particles.

The greatest trend of application in medicine have the nanoparticles of iron, copper, silver, silicon, magnesium, gold and zinc.

The subject matter in this work is nanoparticles of copper and gold, received by means of laser ablation of hard targets in liquid medium.

The aim of exploration, represented in the article, is the estimation of application of the dynamic light scattering method for determination of the range of nanoparticles sizes in the colloidal solution.

For studying of the laser ablation process was chosen the second harmonic of Nd:YAG laser with the wavelength of 532 nm. Special attention was spared for the description of the experiment technique of receiving of nanoparticles.

As the liquid medium ethanol and distillation water were used.

For exploration of the received colloidal system have been used the next methods: DLS, transmission electron microscopy (TEM) and scanning electron microscopy (SEM).

The results of measuring by DLS method showed that colloidal solution of the copper in the ethanol is the steady system. Copper nanoparticle’s size reaches 200 nm and is staying in the same size for some time.

Received system from the gold’s nanoparticles is polydisperse, unsteady and has a big range of the nanoparticle’s sizes. This fact was confirmed by means of photos, got from the TEM FEI Tecnai G2F20 + GIF and SEM Helios NanoLab 660. The range of the gold nanoparticle’s sizes is from 5 to 60 nm. So, it has been proved that the DLS method is authentic for the analysis of the state colloidal system with a small range of partcle’s sizes.

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