Open AccessCO-CRYSTALLIZATION OF C60 AND С70 FULLERENES IN CRYSTAL-SOLVATE [(C70)X+(С60)Y]• TMTSeF•2(C6H6) (х+у=3)
Author(s) -
Maksim A. Blagov,
N. G. Spitsina,
С. В. Коновалихин
Publication year - 2018
Publication title -
izvestiâ vysših učebnyh zavedenij. himiâ i himičeskaâ tehnologiâ/izvestiâ vysših učebnyh zavedenij. seriâ himiâ i himičeskaâ tehnologiâ
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.221
H-Index - 5
eISSN - 2500-3070
pISSN - 0579-2991
DOI - 10.6060/tcct.20165909.3y
Subject(s) - fullerene , crystallization , benzene , molecule , crystallography , crystal (programming language) , materials science , selenium , tetra , chemistry , organic chemistry , medicinal chemistry , computer science , programming language
The compexation of (С70/C60) fullerenes with organic p-donor of electrons tetramethyl-(tetra selenium)fulvalene (TMTSeF) in benzene (С6Н6) was studied. Comparison of experimental and calculated X-ray patterns showed that in the investigated single crystals of [(C70)x+(С60)y]· TMTSeF·2(C6H6) (х+у=3) (1) С70 and C60 fullerens are co-crystallized. IR spectral data and electroconductivity of 1 indicate the absence of the charge transfer on fullerene molecule for complexes under study.