CO-CRYSTALLIZATION OF C60 AND С70 FULLERENES IN CRYSTAL-SOLVATE [(C70)X+(С60)Y]• TMTSeF•2(C6H6) (х+у=3) | Zendy

Maksim A. Blagov | Zendy; Nataliya G. Spitsina | Zendy; С. В. Коновалихин | Zendy

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CO-CRYSTALLIZATION OF C60 AND С70 FULLERENES IN CRYSTAL-SOLVATE [(C70)X+(С60)Y]• TMTSeF•2(C6H6) (х+у=3)

Author(s) -

Maksim A. Blagov,

Nataliya G. Spitsina,

С. В. Коновалихин

Publication year - 2018

Publication title -

izvestiya vysshikh uchebnykh zavedeniy khimiya khimicheskaya tekhnologiya

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.221

H-Index - 5

eISSN - 2500-3070

pISSN - 0579-2991

DOI - 10.6060/tcct.20165909.3y

Subject(s) - fullerene , crystallization , benzene , molecule , crystallography , crystal (programming language) , materials science , selenium , tetra , chemistry , organic chemistry , medicinal chemistry , computer science , programming language

The compexation of (С70/C60) fullerenes with organic p-donor of electrons tetramethyl-(tetra selenium)fulvalene (TMTSeF) in benzene (С6Н6) was studied. Comparison of experimental and calculated X-ray patterns showed that in the investigated single crystals of [(C70)x+(С60)y]· TMTSeF·2(C6H6) (х+у=3) (1) С70 and C60 fullerens are co-crystallized. IR spectral data and electroconductivity of 1 indicate the absence of the charge transfer on fullerene molecule for complexes under study.

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