Open AccessTHERMODYNAMICS OF 4-TERT-BUTYLCALIX[4]ARENE COMPLEXATION WITH SOME SOLVENTS
Author(s) -
О. В. Суров,
Yu. B. Ivanova,
Н. Ж. Мамардашвили
Publication year - 2018
Publication title -
izvestiâ vysših učebnyh zavedenij. himiâ i himičeskaâ tehnologiâ/izvestiâ vysših učebnyh zavedenij. seriâ himiâ i himičeskaâ tehnologiâ
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.221
H-Index - 5
eISSN - 2500-3070
pISSN - 0579-2991
DOI - 10.6060/tcct.20165902.5279
Subject(s) - chloroform , chemistry , dichloromethane , methanol , dimethylformamide , hexane , dimethyl sulfoxide , carbon tetrachloride , ethanol , solvent , butanol , organic chemistry
In given paper the thermodynamics of 4-tert-butylcalix[4]arene complexation with methanol, ethanol, isopropanol, tert-butanol, n-hexane, dichloromethane, chloroform, carbon tetrachloride, dimethyl sulfoxide and dimethylformamide was studied. Enthalpies and entropies of complexation were calculated based on the temperature dependence of the complexation constants.