Open AccessEFFECT OF STERIC ACCESSIBILITY OF EXCHANGE CENTER OF HIGHER QUATERNARY AMMONIUM SALTS AND PLASTICIZER NATURE ON CHARACTERISTICS OF ELECTRODES, REVERSIBLE TO DOUBLE-CHARGED ANIONS
Author(s) -
Е. М. Рахманько,
Yu.V. Matveiychuk
Publication year - 2018
Publication title -
izvestiâ vysših učebnyh zavedenij. himiâ i himičeskaâ tehnologiâ/izvestiâ vysših učebnyh zavedenij. seriâ himiâ i himičeskaâ tehnologiâ
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.221
H-Index - 5
eISSN - 2500-3070
pISSN - 0579-2991
DOI - 10.6060/tcct.20165901.5160
Subject(s) - plasticizer , steric effects , ammonium , selectivity , chemistry , detection limit , ion exchange , inorganic chemistry , electrode , membrane , ion , organic chemistry , chromatography , catalysis , biochemistry
The effect of the steric accessibility of the exchange center of higher quaternary ammonium salts and plasticizer nature on the selectivity and the limit of detection for film electrodes reversible to hydrophilic double-charged anions was studied. It was established the decrease in selectivity coefficients lgKi,jPot by 2.8−3.8 order of magnitude and low detection limit by 2−3 order of magnitude in the series of QAS: TOD≤TC DDP>o-NPDE>1-BN was established. The composition of membranes of ion-selective electrodes was optimized.