Open AccessANALYSIS OF KINETIC CHARACTERISTICS OF BAROMEMBRANE AND ELECTROBARMEMBRANE SEPARATION OF AMMONIUM NITRATE SOLUTION
Author(s) -
С. И. Лазарев,
С. В. Ковалев,
Д. Н. Коновалов,
О. А. Ковалева
Publication year - 2020
Publication title -
izvestiâ vysših učebnyh zavedenij. himiâ i himičeskaâ tehnologiâ/izvestiâ vysših učebnyh zavedenij. seriâ himiâ i himičeskaâ tehnologiâ
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.221
H-Index - 5
eISSN - 2500-3070
pISSN - 0579-2991
DOI - 10.6060/ivkkt.20206309.6196
Subject(s) - membrane , anode , cathode , chemistry , analytical chemistry (journal) , nitrate , electrodialysis , membrane technology , ammonium , aqueous solution , nanofiltration , ammonium nitrate , permeation , inorganic chemistry , chemical engineering , chromatography , electrode , organic chemistry , biochemistry , engineering
The paper presents a generalized analysis of literature data on the current-voltage, omics characteristics and electrical conductivity of membrane systems. Based on an analysis of the literature, it is noted that electrodialysis is a promising method for the separation of solutions for the production of ammonium nitrate. An analysis of literature revealed that the application of an external constant electric field to the membrane separation of solutions containing charge-transporting components (nitrate ions and ammonium ions) causes the directed transfer of cations and anions through the membranes. The studies revealed that with the baromembrane separation of the studied solutions with increasing transmembrane pressure, the specific output stream increases. This is due to an increase in the driving force of the process. For the OFAM-K anode membrane, with an increase in the current density, with the electrobaromembrane separation of the ammonium nitrate solution, the specific output stream decreases, which is associated with a change in the pH value of the acidified anode permeate. nd for the OPMN-P cathode membrane, the specific output stream increases with a change in the pH of the alkalized cathode permeate. A modified mathematical equation is proposed for theoretical calculation of the specific output stream and the retention coefficient of the OFAM-K and OPMN-P nanofiltration membranes. Experimental studies of membrane systems equipped with the anode OFAM-K and the near-cathode OPMN-P membranes from voltage and transmembrane pressure revealed that for the aqueous solution of ammonium nitrate there are two characteristic periods on the current-voltage, omics characteristics and electrical conductivity of the membrane system (the first period is beyond regime, dissociation of water (H+ and OH-) at the phase boundary with the advent of additional electric current carriers, the second is the degradation of the active layer of a semipermeable membrane). When studying the current-voltage characteristics of a membrane system equipped with an anode OFAM-K and a near-cathode OPMN-P membranes, when separating model and technological solutions, a decrease in the total omics resistance of the system is observed, which is associated with the solution throttling process.