Open AccessVapor pressure of water at its triple point
Author(s) -
L. A. Guildner,
Daniel P. Johnson,
Frank E. Jones
Publication year - 1976
Publication title -
journal of research of the national bureau of standards. section a. physics and chemistry
Language(s) - English
Resource type - Journals
eISSN - 2376-5704
pISSN - 0022-4332
DOI - 10.6028/jres.080a.054
Subject(s) - triple point , vapor pressure , distilled water , pressure measurement , water vapor , boiling point , mercury (programming language) , chemistry , analytical chemistry (journal) , bubble point , vapour pressure of water , pressure sensor , materials science , mechanics , thermodynamics , chromatography , physics , bubble , organic chemistry , computer science , programming language
The vapor pressure of water at its triple point was measured with exceptionally high accuracy by realizing it with a special apparatus and measuring the pressure with the NBS precision mercury manometer. The vapor pressure apparatus had a system for circulating the liquid water. Actual triple point conditions were established with a thin sheet of freshly distilled liquid flowing down over an exposed mantle of ice frozen on a vertical well. This technique reduced non-volatile contaminants and the vapor was repeatedly pumped to remove accumulated volatile contaminants. A diaphragm pressure transducer was used to separate the water vapor from the helium used to transmit the pressure to the manometer. The value found for the vapor pressure of water at its triple point was 611.657 Pa with an uncertainty of ± 0.010 Pa from random errors, computed at 99 percent confidence limits. The systematic errors are estimated to be insignificant relative to the random errors.