Open AccessMass spectrometric study of photoionization. X. Hydrogen chloride and methyl halides
Author(s) -
M. Krauß,
James A. Walker,
Ver H. Dibeler
Publication year - 1968
Publication title -
journal of research of the national bureau of standards. section a. physics and chemistry
Language(s) - English
Resource type - Journals
eISSN - 2376-5704
pISSN - 0022-4332
DOI - 10.6028/jres.072a.027
Subject(s) - photoionization , hydrogen halide , halide , chemistry , hydrogen chloride , ion , dissociation (chemistry) , rydberg formula , ionization , atomic physics , photoionization mode , bond dissociation energy , hydrogen , ionization energy , chloride , inorganic chemistry , halogen , physics , alkyl , organic chemistry
Photoionization efficiency curves are obtained for hydrogen chloride and several methyl halides, both ordinary and deuterated, from ionization threshold to 600 Å. Discussion is given on electronic structure of ions, autoionizing Rydberg states, and line-shape behavior. Ionization energies, heats of formation of ions, and bond dissociation energies are tabulated without regard to distribution of energy in internal modes, in relative kinetic energy, or other possible modes.