Open AccessOptical and magnetic spectra of bis-n-propylsalicylaldiminato copper (II)
Author(s) -
Curt W. Reimann,
Gerald F. Kokoszka,
Harry C. Allen
Publication year - 1966
Publication title -
journal of research of the national bureau of standards. section a. physics and chemistry
Language(s) - English
Resource type - Journals
eISSN - 2376-5704
pISSN - 0022-4332
DOI - 10.6028/jres.070a.001
Subject(s) - copper , spectral line , electron paramagnetic resonance , molecule , nuclear magnetic resonance , chemistry , materials science , crystallography , physics , organic chemistry , astronomy
The electronic and electron spin resonance spectra of bis- N -propylsalicylaldiminato copper (II) have been measured. The measurements show that the g -tensor has some rhombic character with g z = 2.225, g x = 2.064, and g y = 2.038. Four d-d transitions were observed in the electronic spectrum at 14,800, 16,800, 19,800, and 22,000 cm -1 . A consistent set of assignments has been made based on the polarization data of the bands. These results are compared to the results from other similar molecules.