Some vibrational-rotational bands of deuterated methanes | Zendy

Harry C. Allen | Zendy; Earle K. Plyler | Zendy

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Some vibrational-rotational bands of deuterated methanes

Author(s) -

Harry C. Allen,

Earle K. Plyler

Publication year - 1959

Publication title -

journal of research of the national bureau of standards section a physics and chemistry

Language(s) - English

Resource type - Journals

eISSN - 2376-5704

pISSN - 0022-4332

DOI - 10.6028/jres.063a.007

Subject(s) - perpendicular , excited state , degenerate energy levels , deuterium , resolution (logic) , atomic physics , ground state , materials science , physics , geometry , mathematics , quantum mechanics , artificial intelligence , computer science

A parallel band at 2,200 cm -1 and a perpendicular band at 2,780 cm -1 of CH 3 D have been observed under high resolution and analysed. The analysis of the perpendicular band revealed the presence of l-type doubling in the doubly degenerate excited state. From the analysis of the parallel band it is found that B 0 = 3.880 cm -1 . A hybrid band of CD 3 H has been observed near 2,600 cm -1 . Both active components, A and E are observed and analysed. The ground state B 0 value found from this analysis is in good agreement with previous determinations.

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