Co—Fe Prussian Blue Analogue Intercalated into Diamagnetic Mg—Al Layered Double Hydroxides | Zendy

Cui-Juan Zhang | Zendy; Takashi Yamamoto | Zendy; Yasuaki Einaga | Zendy

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Co—Fe Prussian Blue Analogue Intercalated into Diamagnetic Mg—Al Layered Double Hydroxides

Author(s) -

Cui-Juan Zhang,

Takashi Yamamoto,

Yasuaki Einaga

Publication year - 2016

Publication title -

nanomaterials and nanotechnology

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.412

H-Index - 21

ISSN - 1847-9804

DOI - 10.5772/63276

Subject(s) - prussian blue , ferrimagnetism , materials science , layered double hydroxides , diamagnetism , antiferromagnetism , ion exchange , cobalt , cyanide , inorganic chemistry , valence (chemistry) , magnetization , ion , condensed matter physics , hydroxide , chemistry , electrochemistry , physics , organic chemistry , electrode , quantum mechanics , magnetic field , metallurgy

A heterostructure of diamagnetic magnesium‒aluminium layered double hydroxides (Mg‒Al LDHs) and photomag‐ netic cobalt‒iron Prussian Blue analogue (Co‒Fe PBA) was designed, synthesized and then designated as LDH‒PB. The cyanide-bridged Co‒Fe PBA was two-dimensionally intercalated into the Mg‒Al LDH template by the stepwise anion exchange method. LDH‒PB showed ferrimagnetic properties with in-plane antiferromagnetic exchange interactions, as well as small photo-induced magnetization by visible light illumination due to the low dimensional structures and the characteristic photo-induced electronic states of the mixed valence of FeIII(low spin, S = 1/2)‒CN‒ CoII(high spin, S = 3/2)‒NC‒FeII (low spin, S = 0)

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