
Synthesis of High-Energy Polymer – Glycidyl Azide Polymer (GAP)
Author(s) -
Anna Kasztankiewicz,
Aleksandra Kogut,
Martyna Jankiewicz,
Paweł Maksimowski
Publication year - 2018
Publication title -
problemy mechatroniki
Language(s) - English
Resource type - Journals
eISSN - 2720-5266
pISSN - 2081-5891
DOI - 10.5604/01.3001.0012.1101
Subject(s) - monomer , polymer , propellant , materials science , azide , chemical engineering , fourier transform infrared spectroscopy , molecular mass , polymerization , polymer chemistry , chemistry , organic chemistry , composite material , engineering , enzyme
Glycidyl Azide Polymer (glycidyl polyazide) (GAP) is one of the best known energetic binders, applicable as a component increasing a calorific value of rocket propellants. In this article, a synthesis of GAP is described allowing to obtain a polymer of different molecular masses. The change of a molecular mass can influence on properties of the obtained compounds. The synthesis was carried out according to an active monomer mechanism. The obtained products were characterized using such methods as FTIR, GPC, MALDI-ToF, TG, and NMR.