Open AccessSimulation of square wave voltammetry of three electrode reactions coupled by two reversible chemical reactions
Author(s) -
Milivoj Lovrić
Publication year - 2017
Publication title -
journal of electrochemical science and engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.236
H-Index - 6
ISSN - 1847-9286
DOI - 10.5599/jese.409
Subject(s) - dimensionless quantity , square wave , voltammetry , chemical reaction , chemistry , square (algebra) , electrode , equilibrium constant , analytical chemistry (journal) , chemical equilibrium , thermodynamics , electrochemistry , physics , voltage , organic chemistry , mathematics , quantum mechanics , geometry
Three fast and reversible electrode reactions that are connected by two reversible chemical reactions that are permanently in the equilibrium are analysed theoretically for square wave voltammetry. The dependence of peak potentials on the dimensionless equilibrium constants of chemical reactions is calculated. The influence of the basic thermodynamic parameters on the square wave voltammetric responses is analysed