Open Access1-D and 2-D coordination networks based on tetrathiacalix[4]arene derivative generated with mercury and cobalt salts
Author(s) -
HURİYE AKDAŞ KILIÇ,
Ernest Graf,
MİR WAİS HOSSEİNİ,
NATHALİE KYRİTSAKAS
Publication year - 2022
Publication title -
turkish journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.239
H-Index - 46
eISSN - 1303-6130
pISSN - 1300-0527
DOI - 10.55730/1300-0527.3431
Subject(s) - chemistry , cobalt , mercury (programming language) , derivative (finance) , metal , coordination polymer , coordination complex , stereochemistry , crystallography , single crystal , crystal structure , inorganic chemistry , organic chemistry , computer science , financial economics , economics , programming language
The combination of four iso- nicotinate appended tetrathiacalix[4]arene ( TCA-1 ) in 1,2-alternate imposed conformation behaving as neutral tectons with Co(II)Cl 2 and Hg(II)Cl 2 metallic salts, leads to the formation of neutral, new coordination networks. Indeed, the tetrasubstituted TCA-1 derivative leads to a 1D coordination polymer with Co(II)Cl 2 and a 2D grid-like network with, Hg(II)Cl 2 . The effect of the nature of the metal used on the dimensionality was demonstrated by X-ray diffraction studies on a single crystal.