Synthesis of Molecular Dodecanuclear Carbon-centered Rhenium Cluster Re12CS17 and its Conducting Properties | Zendy

В.Е. Федоров | Zendy; С. П. Габуда | Zendy; S. G. Kozlova | Zendy; Yakov M. Gayfulin | Zendy; Yuri V. Mironov | Zendy; Maxim R. Rizhikov | Zendy; Н. Ф. Уваров | Zendy

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Synthesis of Molecular Dodecanuclear Carbon-centered Rhenium Cluster Re12CS17 and its Conducting Properties

Author(s) -

В.Е. Федоров,

С. П. Габуда,

S. G. Kozlova,

Yakov M. Gayfulin,

Yuri V. Mironov,

Maxim R. Rizhikov,

Н. Ф. Уваров

Publication year - 2012

Publication title -

croatica chemica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.214

H-Index - 50

eISSN - 1334-417X

pISSN - 0011-1643

DOI - 10.5562/cca1973

Subject(s) - rhenium , cluster (spacecraft) , carbon fibers , chemistry , materials science , nanotechnology , computer science , inorganic chemistry , composite number , composite material , programming language

The unique dodecanuclear cluster compound Re12CS17 was prepared and studied by X-ray, complex impedance method and density functional theory (DFT). The compound is amorphous, possesses semiconducting properties. Computer simulations showed that the Re and S atoms at the external borders of the neighboring molecules Re12CS17 can form sufficiently strong Re S intermolecular bonds, similar to the Mo S intermolecular bonds of cuboctahedron Mo6S8 molecules in the Chevrel phases. (doi: 10.5562/cca1973

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