Open AccessEFFICIENT SYNTHESIS OF PYRANOPYRAZOLE DERIVATIVES USING SILICA GRAFTED COPPER STANNATECATALYST
Author(s) -
S L Sangle,
Dipak R. Tope,
Ashok V. Borhade,
S S Ghumare
Publication year - 2022
Publication title -
journal of advanced scientific research
Language(s) - English
Resource type - Journals
ISSN - 0976-9595
DOI - 10.55218/jasr.202213206
Subject(s) - malononitrile , ethyl acetoacetate , hydrazine (antidepressant) , hydrate , catalysis , yield (engineering) , copper , ethanol , bet theory , hydrothermal circulation , nuclear chemistry , chemistry , hydrothermal synthesis , materials science , organic chemistry , inorganic chemistry , chemical engineering , metallurgy , chromatography , engineering
The CuSnO3:SiO2 catalyst was synthesized by hydrothermal method. The polycrystalline products were analyzed by using various physical investigative techniques including XRD, SEM, TEM and BET surface area. The present study deals with one-pot, four component reaction of aldehydes, malononitrile hydrazine hydrate and ethyl acetoacetate in the presence of catalytic amount of Silica grafted CuSnO3 in ethanol at 70°C to prepare series of pyranopyrazoles. This method gives high yield of pyranopyrazoles in short reaction time with economic availability of the catalyst and easy purification.