Open AccessModeling the kinetic regularities of the preparation of dibutoxyethyl adipates
Author(s) -
А.К. Мазитова,
AUTHOR_ID,
G. К. Аminovа,
I. N. Vikharevа,
AUTHOR_ID,
AUTHOR_ID
Publication year - 2021
Publication title -
elmi əsərlər
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.409
H-Index - 11
eISSN - 2218-8622
pISSN - 2218-6867
DOI - 10.5510/ogp2021si200597
Subject(s) - plasticizer , adipate , adipic acid , yield (engineering) , chemistry , catalysis , kinetics , organic chemistry , polymer , chemical engineering , materials science , polymer chemistry , composite material , physics , quantum mechanics , engineering
Additives are important components of PVC composites, providing polymer modification and retention of its properties throughout the entire period of operation. The development and application of environmentally friendly adipate plasticizers is urgent. The article presents the results of kinetic studies of the esterification of adipic acid with ethoxylated n-butanol of varying degrees of ethoxylation. The effect of various catalysts on the yield of the target ester and the degree of ethoxylation on the rate of the esterification reaction was studied. A mathematical model of the kinetics of the process of obtaining dibutoxyethyl adipates of various degrees of ethoxylation has been developed, which makes it possible to predict the technological indicators of the efficiency of the acid catalyst and the effect of the degree of ethoxylation of the alcohol used. Keywords: adipate plasticizer; kinetics; mathematical model; polyvinyl chloride; prediction; esterification.