Synthesis of UiO-66 materials applied to arsenic adsorption in water
Author(s) -
Nguyen Duc Hai,
Vu Minh Tan,
Nguyen The Huu,
T.T. Nguyen
Publication year - 2021
Publication title -
vietnam journal of catalysis and adsorption
Language(s) - English
Resource type - Journals
ISSN - 0866-7411
DOI - 10.51316/jca.2022.004
Subject(s) - arsenic , arsenate , adsorption , zirconium , fourier transform infrared spectroscopy , metal organic framework , nuclear chemistry , materials science , volume (thermodynamics) , environmental chemistry , inorganic chemistry , chemistry , chemical engineering , metallurgy , organic chemistry , physics , quantum mechanics , engineering
In this study, metal-organic frameworks containing zirconium was successfully synthesized at soft conditions (temperature 25oC and ambient pressure). UiO-66 samples were characterized by XRD, FTIR, SEM, EDX and BET. The SEM-image result showed UiO-66 particles size of 100-200 nm. UiO-66 sample showed the high surface area (1436 m2/g) and high pore volume (0.707 cm3/g). The UiO-66 samples tested were used as an adsorbent to remove aquatic arsenic contamination. UiO-66 materials has a high ability to remove arsenic, reaching 78.82 %. The UiO-66 adsorbent functions excellently across a broad pH range of 1 to 11 and achieves a remarkable arsenate uptake capacity of 294.12 mg/g.
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