Open AccessPolyTEMPO electrocatalyst for organic electrosynthesis of benzonitrile from benzyl alcohol
Author(s) -
Luyen Thi Tran,
Benjamin Schille,
Robert Francke
Publication year - 2021
Publication title -
xúc tác và hấp phụ
Language(s) - English
Resource type - Journals
ISSN - 0866-7411
DOI - 10.51316/jca.2021.015
Subject(s) - benzonitrile , electrosynthesis , benzyl alcohol , electrocatalyst , catalysis , alcohol , chemistry , ammonium acetate , organic chemistry , electrochemistry , electrode , high performance liquid chromatography
Requirements for using Poly (2,2,6,6-tetramethylpiperidinyloxy-4-yl methacrylate) (PolyTEMPO) as an electrocatalyst for the organic electrosynthesis of benzonitrile from benzyl alcohol were investigated. The research results indicated that PolyTEMPO expressed catalytic activity in the electrosynthesis of benzonitrile from benzyl alcohol in the presence of ammonium acetate. The electrosynthesis yield of benzonitrile from benzyl alcohol with PolyTEMPO catalyst reached the maximum value at 35 °C after 18 hours.