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Study on synthesis of Metal-organic Framework ZIF-67 and Its application as an absorbent for Remazol Deep Black (RDB) removal from aqueous media
Author(s) -
Nguyen Thi Thanh Tu,
Tran Vinh Thien
Publication year - 2021
Publication title -
vietnam journal of catalysis and adsorption
Language(s) - English
Resource type - Journals
ISSN - 0866-7411
DOI - 10.51316/jca.2021.006
Subject(s) - zeolitic imidazolate framework , adsorption , metal organic framework , scanning electron microscope , freundlich equation , imidazolate , materials science , aqueous solution , chemical engineering , nuclear chemistry , hydrothermal circulation , specific surface area , langmuir adsorption model , yield (engineering) , metal , chemistry , inorganic chemistry , organic chemistry , composite material , metallurgy , engineering , catalysis
In this work, zeolitic imidazolate framework-67(ZIF-67) was synthesized by using microwave-assisted method. The obtained ZIF-67 was characterized by means of scanning electron microscope (SEM), X-ray diffraction (XRD), and thermal gravity analysis (TG). The microwave-assisted method enabled to fabricate ZIF-67 with high yield rate and high specific surface areas of 1935 m2/g in relatively short time as compared to hydrothermal and solvothermal approaches. The Langmuir and Freundlich isotherm models were utilized to determine the adsorption capacity of ZIF-67. It was found that the adsorption capacity of ZIF-67 for RDB could be as high as 123,5 mg/g.

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