Application of MIL-53(Fe) metal-organic framework material in catalytic wet oxidation of phenol | Zendy

Huynh Thanh Danh | Zendy; Nguyen Huu Nghi | Zendy; Phạm Đình Dũ | Zendy

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Application of MIL-53(Fe) metal-organic framework material in catalytic wet oxidation of phenol

Author(s) -

Huynh Thanh Danh,

Nguyen Huu Nghi,

Phạm Đình Dũ

Publication year - 2021

Publication title -

vietnam journal of catalysis and adsorption

Language(s) - English

Resource type - Journals

ISSN - 0866-7411

DOI - 10.51316/jca.2021.005

Subject(s) - phenol , oxalic acid , catalysis , formic acid , acetic acid , aqueous solution , chemistry , fourier transform infrared spectroscopy , inorganic chemistry , catalytic oxidation , nuclear chemistry , metal , organic chemistry , chemical engineering , engineering

In the present study, MIL-53(Fe) metal-organic framework material was applied as catalyst for phenol oxidation reaction in aqueous solution with H2O2 under UV radiation. The materials were characterized using X-ray diffraction (XRD), and fourier transform infrared spectroscopy (FT-IR). The effects of reaction time, initial phenol concentration, and initial pH of the solution on phenol oxidation reactions were investigated. The results indicated that MIL-53(Fe) could work effectively in the wide pH range from 2 to 10. Phenol was quickly oxidized to form simple organic acids, including acetic acid, formic acid and oxalic acid.

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