THE DETERMINATION OF A STABILITY CONSTANT FOR THE AQUEOUS COMPLEX Zn(OH) 2  0  USING ANODIC STRIPPING VOLTAMMETRY 1 | Zendy

Bradford Wesley L. | Zendy

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THE DETERMINATION OF A STABILITY CONSTANT FOR THE AQUEOUS COMPLEX Zn(OH) 2 0 USING ANODIC STRIPPING VOLTAMMETRY 1

Author(s) -

Bradford Wesley L.

Publication year - 1973

Publication title -

limnology and oceanography

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.7

H-Index - 197

eISSN - 1939-5590

pISSN - 0024-3590

DOI - 10.4319/lo.1973.18.5.0757

Subject(s) - stripping (fiber) , anodic stripping voltammetry , zinc , aqueous solution , chemistry , inorganic chemistry , ion , stability constants of complexes , ionic bonding , analytical chemistry (journal) , electrochemistry , materials science , electrode , chromatography , organic chemistry , composite material

The shift in the potential of the zinc stripping current maximum observed in anodic stripping voltammetry is related to the free energy of the reaction between ionic zinc and a complexing anion. The model was tested using the zinc hydroxyl system; the agreement with experimental results was excellent. The findings suggest the existence of the aqueous complex, Zn(OH) 2 o , which has been reported only once before. The stability constant calculated here is in good agreement with the single published value.

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