Open AccessA microporous metal–organic framework with open metal sites for selective sensing Fe3+, CrO42- and nitrobenzene
Author(s) -
F. M. Wang,
R. Wang,
Yutong Han,
S. Y. Li,
Jian-Hui Man,
Yanyi He,
B. H. Li
Publication year - 2017
Publication title -
bulletin of the chemical society of ethiopia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.288
H-Index - 25
eISSN - 1726-801X
pISSN - 1011-3924
DOI - 10.4314/bcse.v31i2.10
Subject(s) - nitrobenzene , chemistry , luminescence , microporous material , quenching (fluorescence) , nitro , metal organic framework , chromate conversion coating , metal , inorganic chemistry , organic chemistry , adsorption , chromium , fluorescence , catalysis , physics , alkyl , optoelectronics , quantum mechanics
A 3D network with the (42·6·83) topology of metal-organic framework possessing an open 1D channel was synthesized by rigid and planar tetracarboxylic acid 5,5’-(1H-2,3,5-triazole-1,4-diyl)diisophthalic acid (H4L). The luminescent properties of 1 shows highly sensitive response to nitrobenzene, Fe3+ and CrO42- through luminescence quenching effects, making it a promising luminescent sensor for nitro aromatic compounds, Fe3+ and CrO42-