Open AccessComparative Study between D2EHPA and Cyanex 272 as Extractants of Mn(II) from a Leached Liquor Produced by Reductive Leaching of a Pyrolusite Ore with SO<sub>2</sub>
Author(s) -
R. PérezGaribay,
Javier Martínez-Jiménez,
A. UribeSalas,
Antonia Martínez-Luévanos
Publication year - 2012
Publication title -
engineering
Language(s) - English
Resource type - Journals
eISSN - 1947-3931
pISSN - 1947-394X
DOI - 10.4236/eng.2012.49067
Subject(s) - pyrolusite , leaching (pedology) , chemistry , manganese , waste management , pulp and paper industry , metallurgy , nuclear chemistry , environmental science , engineering , organic chemistry , materials science , soil science , soil water
This paper compares the efficiency of D2EHPA and Cyanex 272 to extract the divalent manganese cation from an actual leaching solution obtained by reductive leaching of a low-grade pyrolusite ore, using SO2 gas. The studied variables were the extractant concentration in the organic phase, the pH of the leached liquor and the volume ratio between organic phase and leached liquor. It was observed that D2EHPA is a better extractant than Cyanex272. Therefore, with the best experimental conditions found, both extractants reach a manganese recovery around 95% with five extraction stages conducted under the following conditions: 25?C, O/A = 2, 10% volume of extractant concentration in the organic phase, pH of the leached liquor before the mixing between 8 and 8.5, and one minute of mixing time for each extraction stage