Open AccessNucleation and Growth of b‐Axis Oriented PrBa 2 Cu 3 O 7‐x Thin Films on LaSrGaO 4 (100) Substrates
Author(s) -
Sung Gun Yong,
Suh Jeong Dae
Publication year - 1997
Publication title -
etri journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.295
H-Index - 46
eISSN - 2233-7326
pISSN - 1225-6463
DOI - 10.4218/etrij.97.0197.0048
Subject(s) - nucleation , layer (electronics) , substrate (aquarium) , materials science , crystallography , thin film , transmission electron microscopy , deposition (geology) , diffraction , composite material , chemistry , optics , nanotechnology , geology , physics , organic chemistry , paleontology , oceanography , sediment
Good quality a‐axis oriented thin films of YBa 2 Cu 3 O 7‐x may be grown by the use of a PrBa 2 Cu 3 O 7‐x (PBCO) layer as a template. Here we present a detailed study of the nucleation of the PBCO layer, explaining the orientations observed. It is determined that the wavy surface of a LaSrGaO 4 (LSGO) (100) substrate consists of the {101} planes by observing cross‐sectional transmission electron microscopy images of the interface between the PBCO film and the substrate. The images and selected area diffraction patterns show that a mixed cand b‐axis oriented PBCO layer was initially grown on the substrate, followed by pure b‐axis oriented PBCO growth. We explain that the c‐axis oriented growth is the result of the growth of the PBCO (019) planes on the LSGO (101) planes. We conclude that the nucleation and growth of the PBCO films at the initial stages depends on the crystallographic plane of the substrate surfaces, however, as the film grows further, the kinetics of the deposition process favors b‐axis oriented growth.