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Substituent effects in phosphine ligands
Author(s) -
C. Alicia Renison,
D. Bradley G. Williams,
Alfred Muller
Publication year - 2011
Publication title -
suid-afrikaanse tydskrif vir natuurwetenskap en tegnologie
Language(s) - German
Resource type - Journals
eISSN - 2222-4173
pISSN - 0254-3486
DOI - 10.4102/satnt.v30i1.267
Subject(s) - substituent , steric effects , phosphine , chemistry , nuclear magnetic resonance spectroscopy , stereochemistry , computational chemistry , organic chemistry , catalysis
Vorige studies het getoon dat die eienskappe van die P - atoom in PR₃ - sisteme sensitief is ten
opsigte van veranderinge in sy chemiese omgewing (Miller 2010). Hierdie veranderinge word
meegebring deur byvoorbeeld verandering van die substituent wat die steriese - en/of die elektroniese omgewing steur (Miller 2010).

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