Open AccessRETRACTED: Fabrication and Characterization of Nanospinel ZnCr<sub>2</sub>O<sub>4</sub> Using Thermal Treatement Method
Author(s) -
Salahudeen A. Gene,
Elias Saion,
Abdul Halim Shaari,
Mazliana A. Kamarudeen,
Naif Mohammed AlHada
Publication year - 2015
Publication title -
advanced materials research
Language(s) - English
Resource type - Journals
eISSN - 1662-8985
pISSN - 1022-6680
DOI - 10.4028/www.scientific.net/amr.1107.301
Subject(s) - calcination , materials science , crystallite , analytical chemistry (journal) , spinel , thermal decomposition , particle size , transmission electron microscopy , non blocking i/o , spectroscopy , crystallization , scanning electron microscope , electron paramagnetic resonance , nuclear chemistry , chemical engineering , nanotechnology , chemistry , metallurgy , nuclear magnetic resonance , organic chemistry , physics , quantum mechanics , engineering , composite material , catalysis
RETRACTED PAPER: The fabrication of nanospinel zinc chromite (ZnCr 2 O 4 ) crystals by the means of thermal treatment method from an aqueous solution containing metal nitrates, polyvinyl pyrrolidone (PVP), and deionized water was described in this study. The samples were calcined at various temperatures ranging from 773 to 973 K for the decomposition of the organic compounds and crystallization of the nanocrystals. PVP was used as capping agent to control the agglomeration of the particles. The characterization studies of the fabricated samples were carried out by X-ray diffraction spectroscopy (XRD), transmission electron microscopy (TEM), energy dispersed X-ray spectroscopy (EDX) and electron spin resonance spectroscopy (ESR). The corresponding peaks of Zn, Cr and O were observed in the EDX spectrum of the sample which confirms the formation of ZnCr 2 O 4 . The XRD patterns also confirmed the formation of the single faced nanocrystallines of spinel ZnCr 2 O 4 with a face-centered cubic structure. The average particle size of the synthesized crystals was also determined from the XRD patterns using the Scherers formula which shows that the crystallite sizes increases with increase in calcination temperature and was in good agreement with the TEM images which shows cubical ZnCr 2 O 4 nanocrystals with uniform morphology and particle size distributions. The ESR spectra confirmed the existence of unpaired electron in the fabricated samples and the increase in g-factor and decreases in resonant magnetic field (H r ) were observed as the calcination temperature increases.