Open AccessSíntesis de nuevos líquidos iónicos y evaluación de su rendimiento de lixiviación en la recuperación de cobre y zinc de escorias industriales de latón
Author(s) -
Ayfer Kilicarslan Sahin,
Tuğba Selcen Atalay,
Muge Atbakar,
Nüket Öcal,
Muhlis Nezihi Sarıdede
Publication year - 2016
Publication title -
revista de metalurgia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.195
H-Index - 18
eISSN - 1988-4222
pISSN - 0034-8570
DOI - 10.3989/revmetalm.082
Subject(s) - chemistry , zinc , organic chemistry
Imidazolium-based ionic liquids, 1,3-dibenzylimidazolium trifluoroacetate, 1-benzyl-3-ethylimidazolium trifluoroacetate and 1-benzyl-3-propylimidazolium trifluoroacetate were prepared by simple methods, when compared with those in literature sources, and characterized by IR, NMR and GC-MS and LC-MS. These ILs (Ionic Liquids) were employed as leaching agents in the treatment of industrial copper and zinc bearing slag for the recovery of metals. Results showed that synthesized all novel ionic liquids meet the standard specifications of an ionic liquid. Metal recovery rates decrease with time except for zinc dissolution in 1,3-dibenzylimidazolium trifluoroacetate. 1,3-dibenzylimidazolium trifluoroacetate, when compared with others, is a more effective leaching agent for the treatment of copper and zinc bearing brass slag. Metal recovery rates achieved with this IL are 62.58% for zinc and 24.95% for copper